منابع مشابه
Spinel–rock salt transformation in LiCoMnO4−δ
The transformation on heating LiCoMnO4, with a spinel structure, to LiCoMnO3, with a cation-disordered rock salt structure, accompanied by loss of 25% of the oxygen, has been followed using a combination of diffraction, microscopy and spectroscopy techniques. The transformation does not proceed by a topotactic mechanism, even though the spinel and rock salt phases have a similar, cubic close-pa...
متن کاملPresenting an experimental creep model for rock salt
During the recent decades, the design and construction of underground spaces into rock salt have been particularly regarded for storing petroleum fluids, natural gas, and compressed air energy, and also for disposing nuclear and chemical wastes. The rock salt hosting such spaces will be subjected to various types of monotonic/cyclic, short-term/long-term stresses during the construction and/or ...
متن کاملLayered-to-Rock-Salt Transformation in Desodiated NaxCrO2 (x 0.4)
O3 layered sodium transition metal oxides (i.e., NaMO2, M = Ti, V, Cr, Mn, Fe, Co, Ni) are a promising class of cathode materials for Na-ion battery applications. These materials, however, all suffer from severe capacity decay when the extraction of Na exceeds certain capacity limits. Understanding the causes of this capacity decay is critical to unlocking the potential of these materials for b...
متن کاملB1-to-B2 structural transitions in rock salt intergrowth structures.
The rock salt (B1) structure of binary oxides or chalcogenides transforms to the CsCl (B2) structure under high pressure, with critical pressures P(s) depending on the cation to anion size ratio (R(c)/R(a)). We investigated structural changes of A(2)MO(3) (A = Sr, Ca; M = Cu, Pd) comprising alternate 7-fold B1 AO blocks and corner-shared MO(2) square-planar chains under pressure. All of the exa...
متن کاملMaximum probability domains in crystals: the rock-salt structure.
The present paper studies MX crystals in rock-salt structure (M: Li, Na, K; X: F, Cl, Br, I). They are often described as being formed by ions. Pictures based on quantum mechanical calculations sustain and quantify it. The tools used are (i) the Quantum Theory of Atoms in Molecules, (ii) the Electron Localization Function, and (iii) the maximization of the probability to find in a spatial domai...
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ژورنال
عنوان ژورنال: Nature
سال: 1946
ISSN: 0028-0836,1476-4687
DOI: 10.1038/157623a0